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ACS Appl Mater Interfaces
ACS Appl Mater Interfaces
am
aamick
ACS Applied Materials & Interfaces
1944-8244
1944-8252
American Chemical Society

39162065
10.1021/acsami.4c02772
Research Article
Approaching the Intrinsic Limits of Short Channel Vertical Organic Electrochemical Transistors
https://orcid.org/0009-0007-9024-2626
Galeana Perez Negron Alvaro †
Schander Andreas †
Skowrons Michael ‡
https://orcid.org/0000-0001-9130-5755
Barbosa Henrique Frulani de Paula †
https://orcid.org/0000-0001-5029-3356
Lüssem Björn *†
† Institut für Mikrosensoren, -Aktoren, und -Systeme (IMSAS), Universität Bremen, 28359 Bremen, Germany
‡ Department of Physics, Kent State University, Kent, Ohio 44240, United States
* bluessem@imsas.uni-bremen.de
20 08 2024
28 08 2024
16 34 4523445241
19 02 2024
12 08 2024
07 08 2024
© 2024 The Authors. Published by American Chemical Society
2024
The Authors
https://creativecommons.org/licenses/by/4.0/ Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).

Vertical architectures for organic electrochemical transistors (OECTs), due to their submicrometer channel lengths, have presented themselves as a straightforward design approach for achieving high gm/τ ratios, a figure of merit that assesses the performance of the devices by virtue of their transconductance (gm = dID/dVGS) and switching time constant (τ). However, as the practical limitations of the geometries are overcome, the influence of parasitic phenomena becomes more dominant and limits the performance of the device. One approach to reduce the detrimental effects of parasitic resistance in the drain-source circuit is to use a four-point sourcing technique. Here, vertical OECTs are fabricated with four-point structures to approach the intrinsic limit of these devices. It is shown that this approach improves the saturation behavior of the devices, closing the gap between measured gm and intrinsic transconductance gmi at their peak values. Overall, the results discussed here provide insight into the effects of parasitic resistance on OECTs, which in contrast to field-effect transistors, are not as extensively documented.

organic electrochemical transistors
parasitic resistance
vertical architecture
four-point structures
intrinsic transconductance
electrodeposition
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pmc1 Introduction

Organic electrochemical transistors (OECTs) are biocompatible transducers that have emerged as a promising biosensing technology1 due to their ability to detect and amplify signals in aqueous environments.2 They operate by coupling an electronic circuit with an ionic circuit through an organic mixed-ion-electron semiconductor as a channel material.

The mixed conduction inside the active material differentiates the OECTs from other devices based on the field effect. Ions are transported into and out of the channel in response to changes in the applied gate potential, which modulates output drain current ID. The density of ions injected into the active material can be described by a gate capacitance C, which was shown by Rivnay et al.3 to scale with the total volume of the transistor channel. Overall, the following dependency of the transconductance of the devices in the saturation regime is found:1

where W is the channel width, T is the channel thickness, L is the channel length, μ is the hole mobility in the channel, C* is the volumetric capacitance, VT is the threshold voltage, and Vg is the gate voltage.

Often, the WT/L ratio in eq 1 is adjusted to optimize the performance of the OECTs. However, while increasing the width and thickness of the channel is straightforward when fabricating an OECT, doing so leads to slower response times.4 It has been shown that ionic time constant τ is limited by the charging of gate capacitance C of the device and the resistance of the electrolyte, Rion, leading to a geometric dependence of τ ∝ TWL,4 resulting in a gm/τ ratio that scales as2

This dependency adds complexity to the optimization of an OECT. To design fast, high-performance, high-amplification OECTs, the distance between the drain and source electrodes (L) has to be minimized. However, for conventional OECTs, this is often restricted by the resolution of the lithography process, and a compromise is often made by increasing channel width W to obtain high transconductance while keeping the response times as fast as required.

Vertical organic electrochemical transistors (vOECTs) have garnered a considerable amount of interest as they can overcome the limitations caused by the lithography process. In vOECTs, the drain and source electrodes are placed on top of each other instead of side by side, thereby enhancing the performance while minimizing the spatial footprint. The separating distance between the electrodes is defined by either an insulation layer5,6 or the active material itself.7 The separating layer is usually deposited through a spin coating method, allowing for submicrometer channel lengths and, according to eq 2, higher transconductance and reduced switching times. However, the reduction of intrinsic channel resistance enhances the influence of parasitic resistances in series with the transistor channel, altering the expected steady state characteristics in several ways.8

Precisely identifying the source of these parasitic resistances is essential to reaching the intrinsic performance limit of vertical OECTs. Kaphle et al.9 found that OECTs can be limited by contact resistance at the metallic source/drain electrodes. Using the transmission line method, they showed that the contact resistance depends exponentially on the gate potential, which can explain the characteristic bell-shaped transconductance curve. Donahue et al.6 attributed the observed plateauing of max transconductance with increasing WT/L ratios, contradicting eq 1, to ohmic resistance coming from the metallic interconnect lines in series between the power supply and the semiconductor channel. Furthermore, they concluded that the overlap distance of the active material on top of the electrodes that does not participate in the electronic conduction of the device is detrimental to the on and off switching times of the device. Although documentation of parasitic resistance is found in these reports, focused research to identify the exact source has not yet been conducted.

Recently, a novel vOECT design that aims to achieve high transconductance with minimized response times was proposed. The device takes advantage of the precise control of film thickness when channels of various compositions are grown by electrodeposition.10,11 Previously, we were able to show that devices with PEDOT:PSS [poly(3,4-ethylenedioxythiophene)-poly(styrolsulfonate)] channels present high performance, that is, a high gm/τ ratio. However, the transconductance saturates at high geometrical W/L ratios, leading to a reduction in the gm/τ ratio.4

Here, we study the origin of this worsening performance at large W/L ratios. The vOECTs are characterized using a four-point measurement to minimize the influence of line resistances in series with the channel, allowing for enhanced operation of the active material. Under these enhanced conditions, electropolymerized organic films deposited under different galvanostatic conditions, under different deposition times, and using different precursor solutions are characterized. Overall, we show that the four-point measurement increases the device performance drastically. Furthermore, variances of film morphology resulting from different deposition preconditions only weakly influence the performance. It is argued that this insensitivity to the deposition conditions results in small device-to-device variations and high reproducibility of vOECTs.

2 Results

2.1 Structure of Vertical OECTs

The OECT design is described in detail in ref (4). The cross-section and top view images of the vOECTs are shown in panels a and b, respectively, of Figure 1. A cross-sectional scanning electron microscopy image is shown in Figure S1, and more morphological characterization is shown in ref (4). Ring-shaped electrodes are used to maximize channel width W by increasing the number of concentric rings while keeping a small footprint. A polyimide insulation layer, 350 or 125 nm thick, separates the drain and source electrodes and defines channel length L.

Figure 1 Device setup. (a) Cross section of the vertical OECT. A circular gold electrode on the bottom and a ring-shaped one on the top form the source and drain electrodes, respectively. The source and drain are separated by a 350 or 125 nm thin polyimide (PI) passivation layer, defining channel length L. PEDOT:PSS is grown by electropolymerization on top of the source and drain electrode. Adapted with permission from ref (4). (b) Top view of the vOECT design. To reduce the device footprint, the top electrode has a ring-shaped form. The number of rings determines channel width W. Each electrode has an additional thin probe structured on the same metallic layer connected to a different interconnection pad to measure the potential drop at the channel. (c) Circuit diagram of the resulting architecture.

To realize the four-point structure, two additional thin probes (probes A and B in Figure 1b) are added close to the channel of the device to measure the potential drop close to the active device. As the potential is measured with a voltage probe with high input resistance, the potential applied between the source and drain can be measured without the influence of parasitic resistance coming from the metallic lines and voltage source (cf. Figure 1c). The drain-source voltage is applied through two large probes (labeled forces A and B). The sourcing strategy takes the measured potential drop at the channel and uses it as feedback by comparing it to the programmed drain voltage at the voltage source. This virtually eliminates the gate voltage-dependent resistance in series with the PEDOT:PSS channel and any other resistance influence from the source, interconnections, or wires.

The PEDOT:PSS films used in the vOECTs are electropolymerized on the surface of both source and drain electrodes simultaneously, following the methods of Cui and Martin12 and Starbird et al.13 A visible–near-infrared spectrum comparing the traditional PEDOT:PSS mixture deposited by spin coating [with additives ethylene glycol, dodecylbenzenesulfonic acid and (3-glycidyloxypropyl)trimethoxysilan]14−16 and the electrodeposited version used in this work is available in Figure S2. Although the electrodeposited PEDOT:PSS shows higher absorbance for wavelengths above 900 nm, indicating a polaron and bipolaron density higher than that of the spin-coated counterpart, the overall characteristic is identical.17

The thickness of the films is varied by using different conditions during the electrodeposition of the films. The varied parameters are current density J, deposition time t, and the composition of the precursor solution. Increasing either current density J or deposition time t results in thicker channels, which is confirmed by the increase in opacity observed in Figure 2.

Figure 2 Varying the PEDOT:PSS morphology. Images of vOECTs with a channel width W of 1.74 mm for different electropolymerization conditions. The product of the current density and time is proportional to the thickness of the films (T).

2.2 Steady State Characterization

Figure 3 shows the output characteristics of a transistor grown by electropolymerization for 60 s at a current density J of 5 μA/mm2 with a channel width W of 660 μm. The measurement with two-point voltage sourcing (Figure 3a) shows that the saturation region is reached for only higher gate voltages, i.e., stronger depletion of the channel. For lower gate voltages, the drain current continues to increase linearly even at higher drain potentials, i.e., for most voltages (VDS, drain-source voltage; ID, drain current).

Figure 3 Output characteristics of vOECTs. Dependence of the drain current on the drain voltage for different constant gate voltages for a transistor with a width W of 660 μm and a length L of 350 nm that was electropolymerized for 60 s with a constant current density of 5 μA/mm2 measured with (a) two and (b) four points.

Implementing four-point sourcing (Figure 3b) not only increases the overall drain current but also improves the saturation behavior of devices. Overall, smaller drain voltages are needed to reach a behavior similar to that for the two-point measurement.

The transfer characteristics and transconductance of the vOECTs for two- and four-point measurements are shown in Figure 4. When the voltage is sourced in a standard fashion (i.e., using two probes only), drain current ID saturates at negative gate voltages VGS. The saturation sets in earlier (that is, at less negative voltages) for wider transistor channels, leading to a shift of the characteristic toward more positive voltages for wider channels (Figure 4a).

Figure 4 Steady state characteristics of vOECTs. Transfer characteristics for three transistors with increasing channel widths measured at a drain voltage VDS of −0.3 V that were electropolymerized for 30 s with a constant current density of 5 μm/mm2, measured in the (a) two-point and (b) four-point geometries. The transistors measured with four points show an enhanced ON current. Transconductance characteristics with gate voltage measured with (c) two and (d) four points. The absolute maximum of the characteristic bell curve shifts toward higher values when measuring with two points, whereas no shift is observed in the four-point measurement geometry.

This characteristic saturation behavior can be explained by the model of Chou and Antoniadis.18 The differential of the drain current (dID) can be written as3

4

where VDS′ and VGS′ are the internal drain-source and the gate-source voltages, respectively, that are applied to the transistor, i.e., without any voltage drop across parasitic drain RD and source RS resistances (cf. Figure 5). is the intrinsic transconductance of the transistors, which is not degraded by parasitic resistances, the drain-source conductance, which can be approximated by the slope of the output characteristics shown in Figure 3. Internal voltages VDS′ and VGS′ are related to externally applied voltages VDS and VGS, respectively, by5

6

It follows for the externally measured transconductance 7

Figure 5 Modeling parasitic effects on device performance. Equivalent circuit used to discuss the influence of parasitic resistances RD and RS following the results of Chou and Antoniadis.18

Equation 7 shows that ideally, the transfer characteristic is measured in the saturation regime, i.e., at gdi = 0. For diminishing parasitic resistances (RS = RD = 0), the measured transconductance will equal the intrinsic one, i.e., gm = gmi.

Here, however, neither is gdi ≈ 0 nor can the series resistances at the source and drain (RS and RD, respectively) be neglected. Whenever the drain current ID is increased by a decrease in gate voltage VGS (or application of a more negative VGS), internal drain voltage VDS′ decreases (cf. eq 5), ultimately below the pinch-off voltage. Hence, the transistor is not operating in the saturation regime anymore, and drain-source conductance gdi increases with a decrease in VGS. Once drain-source conductance gdi becomes large compared to 1/(RS + RD), the transfer characteristic saturates and gm decreases to zero, as indeed observed experimentally in panels a and c of Figure 4.

As one can see in Figure 4a, the saturation in the transfer characteristic sets in later for a smaller channel width. This, again, is in line with eq 7, as intrinsic transconductance gmi, channel transconductance gdi, and the pinch-off voltage separating the saturation from the linear regime are expected to increase with channel width. Therefore, the transconductance levels off earlier (at less negative voltages). This effect also causes the characteristic transconductance bell curve to become narrower and shift toward the right (Figure 4c).

In contrast, when the drain-source voltage is sourced using the four-point structure, RS and RD can be approximately neglected. Indeed, it is observed that instead of a shift in the gate voltage of the transfer characteristic, the drain current is merely modulated by the channel width; i.e., the drain current increases with the channel width (Figure 4b). Consequently, the position of the maximum transconductance remains at the same gate voltage value, approximately −0.05 V (Figure 4d), and does not shift.

Peak transconductance gm,max is plotted versus geometric ratio W/L in Figure 6. The peak transconductance shows an almost linear increase at low W/L ratios but levels off for larger W/L ratios. The apparent increase in gm,max with W/L for W/L values of <1000 is larger for the four-point measurement, whereas the saturation of gm,max happens earlier, i.e., at smaller W/L ratios.

Figure 6 Scaling of transconductance with the W/L ratio. Dependence of the maximum transconductance on the W/L ratio for transistors electropolymerized with a current density J of 0.5 μA/mm2 for a t of 30 s and measured at a drain voltage VD of −0.5 V. Symbols show gm,max values for four- and two-point sourcing. The dashed lines are simulations of an OECT according to the Bernards model19 with a hole mobility μ of 2 cm2 V–1 s–1, a volumetric capacitance C* of 50 F cm–3, a threshold voltage VT of 0.5 V, and a thickness T of 100 nm, including the effect of parasitic resistance (cf. eq 8). It is assumed that the maximum transconductance is found at a VGS′ of −0.05 V (cf. Figure 4d). The maximum transconductance data measured with four points can be fitted by the model data more accurately than the data measured with two points.

The data shown in Figure 6 can be modeled according to eq 7. As the peak transconductance is plotted, i.e., before the transconductance decreases because of the drain-source conductance, the approximation gdi ≪ 1/(RS + RD) is used.188

The data measured with four points fit the model with great accuracy; i.e., the assumption of a small drain-source conductance is justified. The remaining parasitic source resistance amounts to 5.5 Ω, and a channel thickness T of 100 nm is assumed. However, the approximation does not work as well for the two-point measurements. Here, the remaining gdi (cf. Figure 3) is still significant at low W/L ratios, leading to a stronger influence of parasitic resistance.

Figure 6 shows that only by using the four-point measurement setup can the intrinsic performance of vOECTs be reached, at least at small W/L ratios. Hence, in the following, we try to optimize this performance by optimizing the electropolymerization conditions.

Figure 7 shows the dependency of transconductance on the W/L ratio for transistors electropolymerized with different deposition current densities and times. All of these measurements were taken using four-point voltage sourcing. For all variations, a plateau at W/L ratios of >1000 at a gm,max of ∼140 mS is found. The data can as well be fitted by eq 8 using a source resistance RS of 7 Ω and a thickness T of 100 nm. While different deposition parameters are used, all data sets follow a similar trend. This suggests that for this architecture, a deposition time of 30 s is sufficient to produce a channel with the maximum amplification capabilities. Furthermore, there is no clear difference between films deposited by using different current densities J. Overall, this result suggests that using longer deposition durations and higher current densities will result in thicker films (Figure 2) that, however, do not show any increase in transconductance. This is in line with our previous report,4 which showed that the current transport in these vOECTs is limited to a small cavity between the source and drain electrode. Once this cavity is filled, a maximum transconductance is reached.

Figure 7 Scaling of transconductance with W/L ratio under different electropolymerization conditions. Dependency of maximum transconductance on current density and W/L ratio for transistors electropolymerized for (a) 30, (b) 60, and (c) 180 s. The data are obtained at a drain voltage VD of −0.5 V. The lines plotted are simulations of an OECT according to the Bernards model19 with a hole mobility μ of 2 cm2 V–1 s–1, a volumetric capacitance C* of 50 F cm–3, a threshold voltage VT of 0.5 V, and a thickness T of 100 nm. The considered gate potential (VGS′) is −0.05 V.

3 Four-Point Measurement to Benchmark the Performance of Different Geometries

Vertical organic electrochemical transistors are attracting attention for being a straightforward approach for improving the gm/τ ratio, as it is expected to inversely scale with the square of the channel length. The four-point sourcing approach to characterize vOECTs as shown here ensures that results from different OECT designs can be compared fairly. Using the gm/τ ratio as a figure of merit, the best performing transistors are obtained here for a channel width W of 90 μm (i.e., for devices with only one drain ring), reaching a level of (gm = 79 mS, τon = 275 μs, and τoff = 94 μs). This level is almost twice that previously reported.4 Increasing the channel width by the addition of more rings (cf. Figure 1b) increases gm,max, but the gap between each ring adds to the channel capacitance and possibly adds parasitic resistance leading to a decrease in gm/τ.

Vertical architectures are good for not only strong amplification capabilities and fast response times but also reducing the footprint of devices. For example, Facchetti et al.7 normalized the transconductance of their vOECTs with the footprint area, reaching a gm,A of 226 μS μm–2. When our results are normalized to their footprint, the best vOECTs reach a gm,A of 51 μS μm–2. Because this architecture takes advantage of the cavity created between the drain and source electrodes during the lithography process, the footprint can be optimized by simplifying the device design, which is expected to result in an improvement in both mentioned figures of merit (gm/τ and gm,A).

4 Conclusion

Exploring the limits of channel length scaling in vertical OECTs comes with the stronger influence of parasitic resistance. Understanding their effects on performance is important, as it allows for a better definition of design rules for OECTs. Here, we have successfully presented an experiment that can virtually eliminate most of the parasitic line resistance, allowing the measurements to be affected by only a small series resistance, which might stem from the contact resistance of the active material or remaining resistances of the metallic electrodes.

Using the four-point measuring technique, we can for the first time characterize the intrinsic performance of the vOECT, which in two-point measurements is always degraded by parasitic effects. This allows us to study the influence of deposition conditions (or any differences in the organic semiconductor) on device performance, in particular, the deposition current density and deposition times. Although these parameters are important for controlling the film thickness, they do not affect the transconductance of our devices. This is in line with previous results4 that show that only a small cavity between the source and drain electrode is participating in the behavior of the drain current.

Overall, this approach allows for closer observation of the intrinsic behavior of the active material in the short channels of vOECTs, free of external factors. We expect that the result can be extended to other material systems, e.g., spin-coated materials. However, the limitation from parasitic resistances might become relevant at larger potentials only, in particular for accumulation type OECTs, which tend to show a smaller transconductance gm and better saturation behavior (i.e., higher gdi). Therefore, more engineering studies on the improvement of contact conductivity on OECTs need to be performed to further overcome the limiting factors on their performance, as has been done for organic field-effect transistors (OFETs).20−23

5 Methods

5.1 Device Fabrication

The vOECTs are structured on 4 in. silicon wafers coated with a 500 nm thick silicon oxide layer in the IMSAS ISO-6 cleanroom. First, a 5 μm thick polyimide layer (U-Varnish S, UBE Corp.) is spin-coated and cured using a vacuum hot plate to create a base insulation layer. A 250 nm thick gold layer is afterward deposited and structured using magnetron dc sputtering (Pro Line PVD 75, Kurt J. Lesker Company Ltd.), photolithography (AZ 1518, MicroChemicals GmbH), and wet chemical etching (Au etch 200, NB Technologies GmbH) to create the source electrodes and sense A probes. Then, two thin layers of polyimide of 350 or 125 nm are spin-coated and cured to insulate the source electrodes and define the channel length of the transistor. A second gold layer is deposited using the same processes described above to structure the drain electrodes and sense B probes. To insulate the conducting paths and define the area for electropolymerization of PEDOT:PSS, another 5 μm thick polyimide layer is spin-coated and cured. A short (30 s) oxygen RIE plasma treatment (STS ICP) is performed directly before coating of polyimide to significantly improve the adhesion between consecutive polyimide layers. The top insulation layer is then structured together with the thin polyimide layer by using photolithography (AZ 10XT, MicroChemicals GmbH) and oxygen RIE plasma (STS ICP). After wafer dicing, the electropolymerization process is performed. For electrodeposition of PEDOT:PSS, a monomer solution of 10 mM EDOT (3,4-ethylenedioxythiophene, Sigma-Aldrich) and 2 wt % NaPSS [poly(sodium 4-styrenesulfonate), MW 70 000, Sigma-Aldrich] dissolved in deionized (DI) water is used. Galvanostatic conditions of 5 or 10 μA/mm2 are applied between the samples and the platinum counter electrode. For a more homogeneous coating, the monomer solution is stirred slowly using a magnetic stirrer. The source and drain electrodes are coated simultaneously with PEDOT:PSS. After coating, the samples are cleaned in DI water and dried with nitrogen. The coating thickness is controlled by the electropolymerization time and current density.

5.2 Electrical Characterization

Four-point probe measurements were performed with a Keithley Series 2400 SourceMeter, configured with the four-wire remote sensing setup in one SMU to source the drain voltage. A voltage sweep was configured and supplied by the second SMU to an ∼1 cm2 PEDOT:PSS gold gate electrode to obtain the transfer characteristics using Ringer’s solution (B. Braun) as the electrolyte. The transconductance was determined by a central difference derivative and a moving average to reduce the noise.

Transient measurements were performed with a Tektronix oscilloscope using an amplifier circuit to convert and amplify measured currents to voltage signals. On and off switching times were determined by the time to switch from the ON drain current to 63% of the OFF current and vice versa.

Supporting Information Available

The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acsami.4c02772.Additional characterization of materials and devices, including a cross section of the vOECT channel and visible–near-infrared spectra of electropolymerized PEDOT:PSS (PDF)

Supplementary Material

am4c02772_si_001.pdf

The authors declare no competing financial interest.

Acknowledgments

The authors acknowledge Melanie Kirsch for her contribution in mask fabrication and metal sputtering during lithography.
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